数字农科院2.0

Enhancing sorption of layered double hydroxide-based magnetic biochar for arsenic and cadmium through optimized preparation protocols

文献类型: 外文期刊

作者: Peng Lyu;Lianfang Li;Jinli Huang;Jing Ye;Changxiong Zhu;Jinni Xie;Zihan Wang;Mengqi Kang;Ao Yan

作者机构:

关键词: As(III) and Cd(II);Modified biochar;Performance-characterization relationship;Preparation protocols;Sorption

期刊名称: Bioresource Technology

ISSN: 0960-8524

年卷期: 2023 年 388 卷

页码:

收录情况: SCIE(2023版) ; ; EI(2023版)

摘要: The impact of multiple preparation protocols on properties and performance of modified biochar remains unclear. This study prepared layered double hydroxide (LDH)-based magnetic biochars (LMBCs) with different LDH loading rates (LLR), pyrolysis temperatures, and biomass sources to explore their performance-characterization relationships toward As(III) and Cd(II). Higher LLR and pyrolysis temperature enhanced LMBCs᾿ adsorption capacities by increasing specific surface area (SSA) and metal/O-containing groups. Hence, LMBC produced at 2:1 LLR (LDH: magnetic biochar) and 800 ℃ pyrolysis exhibited maximum adsorption over 2 times that of LMBC with 0.5:1 LLR and 400 ℃ pyrolysis. Bamboo-sourced LMBC demonstrated superior adsorption than sewage sludge and garlic-sourced LMBCs due to its increased SSA, enabling a higher loading of nano-LDH. Adsorption of As(III) and Cd(II) onto LMBCs was governed by metal-mineral and metal-containing group through co-precipitation and complexation. This study provides a reference for adjusting the preparation protocols to improve sorption performance of modified biochar toward multiple heavy metals.

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