文献类型： 外文期刊

作者： Weishan Zheng;Junyi Zhou;Fang Chen;Shuchen Tu、徐欣欣、Hongwei Huang

作者机构：

关键词： BPA degradation;CdBiO2I;Self-grafting;Surface local electric field;Visible-light photocatalysis

期刊名称： Surfaces and Interfaces

ISSN： 2468-0230

年卷期： 2025 年 62 卷

页码：

收录情况： SCIE（2025版）

摘要： Photocatalysis technology has promising application prospects in the treatment of water pollution. However, at present, the performance of photocatalytic pollutant degradation of photocatalysts is limited by the high recombination rate of photogenerated carriers and the low utilization rate of visible light. In this work, we develop a surface-I ion self-grafted CdBiO2I (CBOI-I) as an efficient visible-light photocatalyst via a facile precipitation route under ambient atmosphere. Compared with CdBiO2I, the self-grafted I ions allows CdBiO2I a grafting-concentration dependent light response range. With the increase in the grafting concentration of I ion, the absorption edge of CBOI-I red-shifts from 580 nm to 650 nm, with a band gap decrease of around 0.2 eV. In-situ Kelvin-probe force microscopy, photoluminescence spectra, photoelectrochemical tests and DFT calculation demonstrate, that the surface self-grafting of I ion on CdBiO2I enables the formation of surface localized electric field on the surface of the photocatalyst, which efficiently promotes the separation and transfer of photogenerated holes and electrons, producing more superoxide radicals and holes as reactive species. Thus, the optimal CBOI-I (CBOI-I4) exhibits an excellent photocatalytic performance for degradation of bisphenol A upon visible light illumination, in which the degradation rate reaches 94 % within 60 min, beyond 4.9 times that of CdBiO2I. Besides, other contaminants, including tetracycline hydrochloride, aureomycin hydrochloride, rhodamine B, and methyl orange are also effectively degraded, demonstrating the photodegradation universality of CBOI-I. This work offers an alternative route for developing high-efficiency and broad-spectrum responsive via surface modification.

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