数字农科院2.0

Based on theoretical design simultaneous analysis of multiple neonicotinoid pesticides in beeswax by deep eutectic solvents extraction combined with UHPLC-MS/MS

文献类型： 外文期刊

作者： Mu, Guodong;Yan, Sha;Pan, Fei;Xu, Haitao;Jing, Xu;Xue, Xiaofeng

作者机构：

关键词： Beeswax;Neonicotinoid pesticides;Deep eutectic solvent;Conduct or-like screening model for real sol- vents;Molecular dynamics simulation;LC-MS/MS

期刊名称： FOOD CHEMISTRY-X

ISSN： 2590-1575

年卷期： 2025 年 25 卷

页码：

收录情况： SCIE（2025版） ; ; EI（2025版）

摘要： Beeswax, an FDA-approved component, has been extensively applied in feed, pharmaceutical, and food industries. The occurrence of neonicotinoid pesticides in beehive systems and their residues in beeswax have caused safety risks. Therefore, establishing a detection method for neonicotinoid pesticide residues in beeswax is crucial for ensuring its quality. The superhydrophobic property of beeswax makes it a challenge to develop suitable determination methods. In this work, we determined Proline and Oxalic acid as a suitable deep eutectic solvent (DES) to extract neonicotinoids from beeswax through theoretical design and verification tests. Systematic molecular dynamics simulations confirmed that hydrogen bonding and van der Waals forces facilitate the migration of neonicotinoid pesticides from beeswax into the DES. Performance analysis of the method revealed that the DES extraction combined with UHPLC-MS/MS approach exhibited excellent detection capabilities. It was applied to real beeswax sample analysis with the characteristics of simpleness, quickness, environmental friendliness, and high throughput.

分类号：

  • 相关文献

[1]Determination of organochlorine pesticides in propolis by gas chromatography-electron capture detection using double column series solid-phase extraction. Chen, Fang,Chen, Lanzhen,Zhou, Jinhui,Xue, Xiaofeng,Zhao, Jing,Wang, Qiang.

[2]Gas Chromatographic-Mass Spectrometry and Chemometric Analysis for Detection and Quantification of Paraffin in Beeswax. Chen, Fang,Chen, Lanzhen,Zhao, Jing,Xue, Xiaofeng,Wu, Liming,Zheng, Chuangmu.

[3]Solid-phase purification and extraction for the determination of trace neonicotinoid pesticides in tea infusion. Zhang, Minglu,Chen, Hongping,Zhu, Li,Wang, Chuanpi,Ma, Guicen,Liu, Xin,Zhang, Minglu,Chen, Hongping,Zhu, Li,Wang, Chuanpi,Ma, Guicen,Liu, Xin.

[4]Efficient degradation of imidacloprid by surface discharge cold plasma: Mechanism of interaction between ROS and molecular structure and evaluation of residual toxicity. Ni, Jia-Bao,Jia, Xiao-Fang,Zhang, Jun-Ying,Ding, Chang-Jiang,Tian, Wen-Li,Peng, Wen-Jun,Zielinska, Sara,Xiao, Hong-Wei,Fang, Xiao-Ming. 2024

[5]Enhanced insecticidal activity and bioavailability of thiacloprid from pH-responsive porous MPN(Fe)@ZIF-8 nanocarrier. Miao Wang,Donghui Xu,Ying Zhang,Jie Zhou,Zhihao Lin,Yiming Zhao,Xin Ding,Bin Sheng,Xiaobin Wen,Xiao Song,Ge Chen,Xiaomin Xu,Xin Yang,Guangyang Liu. 2025

[6]阿维菌素在柑桔和土壤中的残留及其消解动态. 张娇娇,刘炎,叶玉凤,赵其阳,彭震宇,焦必宁,王成秋. 2017

[7]基于分散固相萃取液相色谱-串联质谱法测定大米中8种真菌毒素. 孙伟华,杨欢,曹赵云,马有宁,秦美玲,柴爽爽,陈铭学. 2017

[8]大丽轮枝菌分泌蛋白提取方法比较. 肖红利,桂月晶,祁伟彦,陈捷胤,李蕾,徐明,戴小枫. 2014

[9]LC-MS/MS检测饲料中二甲氧苄啶、甲氧苄啶和二甲氧甲基苄啶方法的建立. 杨亚军,刘希望,李冰,孔晓军,李世宏,秦哲,杜文斌,李剑勇. 2015

[10]黄瓜根分泌物中的7;8-苯并黄酮及其对枯萎病发生的影响. 李世东,郭荣君. 2010

[11]液相色谱-串联质谱法检测鸡蛋中金刚烷胺残留. 汤晓艳,陈东宇,周剑,毛雪飞,邱静,王敏. 2014

[12]晋麦47幼苗中一个水分胁迫应答蛋白的SDS-PAGE和Nano LC-MS/MS鉴定. 范锋贵,张晓科,任万杰,王晓龙,叶石,付晓洁,王宏礼,朱建楚. 2012

[13]黄瓜根分泌物中的7,8-苯并黄酮及其对枯萎病发生的影响. 李世东,郭荣君. 2010

[14]玉米DDGS中抗生素残留分析. 姚婷,秦玉昌,吴宁鹏,彭丽,孙丹丹,谷旭. 2014

[15]荷斯坦奶牛瘤胃微生物脲酶的分离与鉴定. 赵圣国,王加启,刘开朗,李旦,于萍,卜登攀. 2010

[16]卷丹百合及其鳞茎中秋水仙碱含量的测定. 陈凯,王米,何菁琦,张赛奇,许璟. 2020

[17]利用多功能针式过滤器快速检测油菜和苹果中68种农药及代谢物残留. 贾琪,王纯强,马蕊,王宇彤,钱永忠,邱静. 2019

[18]农产品与饲料中T-2毒素免疫亲和柱净化-液相色谱串联质谱检测技术研究. 李静,马飞,李培武,张奇,丁小霞,张文. 2014

[19]LC-MS/MS测定青稞中氨基酸的含量及主成分分析. 王猛强,邱城,张唐伟,李腾飞,李壮,王淼,曹振,王珊珊,郑鹭飞,金茂俊,王静,邵华,金芬,佘永新. 2022

[20]QuEChERS联合LC-MS/MS测定土壤及蚯蚓中吡虫啉及异丙甲草胺13种代谢产物. 符芙蓉,赵丽霞,李晓晶,叶会科,孙扬,李永涛. 2023

作者其他论文 更多>>