数字农科院2.0

Matrix Effect Evaluation and Method Validation of 181 Pesticides in Three Types of Tea Using Gas Chromatography-Tandem Mass Spectrometry

文献类型： 外文期刊

作者： Zhang, Danyang;Yang, Xiaoning;Zhu, Lei;Yu, Miao;Chen, Menglu;Wang, Qinghua;Jiang, Ying;Chen, Hongping;Chai, Yunfeng

作者机构：

关键词： Tea;Gas chromatography-tandem mass spectrometry;Pesticide residues;Matrix effect

期刊名称： FOOD ANALYTICAL METHODS

ISSN： 1936-9751

年卷期： 2025 年

页码：

收录情况： SCIE（2025版） ; ; EI（2025版）

摘要： Differences in matrix effects caused by different types of tea in the analysis of pesticide residues via gas chromatography-tandem mass spectrometry (GC-MS/MS) have not been well studied. This study evaluated the matrix effects of 181 pesticides in three types of tea with different fermentation degrees using GC-MS/MS. The median values of the matrix effects of 181 pesticides for green tea, black tea, and dark tea were 179%, 26%, and 197%, respectively. Among these pesticides, 58 exhibit significant differences in their matrix effects across the three tea matrices. A GC-MS/MS method for 181 pesticide residues in tea was validated using the matrix-matched standards prepared from blank tea samples with a fermentation degree consistent with that of the test samples. The results showed that the recoveries for more than 95% of the pesticides ranged from 60 to 120%, with relative standard deviations (RSDs) less than 25%. The limits of quantitation (LOQs) spanned a range from 5 to 50 mu g/kg. When applied to the detection of real-world tea samples, this method achieved a significant reduction in detection errors for 9 pesticides by 21.66-100%. It is recommended that the matrix matched standard solutions be prepared from blank tea with the same fermentation degree as the test samples for the analysis of pesticide residues in different types of tea via GC-MS/MS.

分类号：

  • 相关文献

[1]An Integrated Strategy for Purification by Combining Solid-Phase Extraction with Dispersive-Solid-Phase Extraction for Detecting 22 Pesticides and Metabolite Residues in Fish. Yage Guo,Jie Zhang,Jun Xu,Xiaohu Wu,Fengshou Dong,Xingang Liu,Yongquan Zheng. 2021

[2]Determination of 16 phthalate esters in tea samples using a modified QuEChERS sample preparation method combined with GC-MS/MS. Yin, Peng,Liu, Xin,Chen, Hongping,Pan, Rong,Ma, Guicen.

[3]Occurrence and Residue Pattern of Phthalate Esters in Fresh Tea Leaves and during Tea Manufacturing and Brewing. Liu, Pingxiang,Chen, Hongping,Gao, Guanwei,Hao, Zhenxia,Wang, Chen,Ma, Guicen,Chai, Yunfeng,Zhang, Lin,Liu, Xin,Liu, Pingxiang,Gao, Guanwei,Zhang, Lin,Chen, Hongping,Hao, Zhenxia,Wang, Chen,Ma, Guicen,Chai, Yunfeng,Liu, Xin.

[4]Determination of 16 Polycyclic Aromatic Hydrocarbons in Tea by Simultaneous Dispersive Solid-Phase Extraction and Liquid-Liquid Extraction Coupled with gas Chromatography-Tandem Mass Spectrometry. Chen, Hongping,Gao, Guanwei,Liu, Pingxiang,Pan, Rong,Liu, Xin,Lu, Chengyin.

[5]Determination for major chemical contaminants in tea (Camellia sinensis) matrices: A review. Li, Xin,Zhang, Zhaowei,Li, Peiwu,Zhang, Qi,Zhang, Wen,Ding, Xiaoxia,Li, Xin,Zhang, Zhaowei,Li, Peiwu,Zhang, Qi,Ding, Xiaoxia,Li, Xin,Zhang, Zhaowei,Li, Peiwu,Zhang, Qi,Li, Peiwu,Zhang, Wen,Ding, Xiaoxia,Zhang, Wen,Ding, Xiaoxia.

[6]A Modified QuEChERS Sample Preparation Method for the Analysis of 70 Pesticide Residues in Tea Using Gas Chromatography-Tandem Mass Spectrometry. Chen, Hongping,Yin, Peng,Wang, Qinghua,Jiang, Ying,Liu, Xin,Chen, Hongping,Wang, Qinghua,Jiang, Ying,Liu, Xin.

[7]Rapid Determination of Paclobutrazol in Fruits by QuEChERS Cleanup and Gas Chromatography-tandem Mass Spectrometry. Song Ying,Pan Jia-Rong,Song Ying,Zhang Yao-Hai,Huang Xia,Jiao Bi-Ning. 2011

[8]MASS SPECTRAL FRAGMENTATION PATHWAYS OF PHTHALATE ESTERS BY GAS CHROMATOGRAPHY-TANDEM MASS SPECTROMETRY. Yin, Peng,Chen, Hongping,Liu, Xin,Wang, Qinghua,Jiang, Ying,Pan, Rong.

[9]Simultaneous determination of aflatoxin M-1, ochratoxin A, zearalenone and alpha-zearalenol in milk by UHPLC-MS/MS. Huang, L. C.,Zheng, N.,Wen, F.,Cheng, J. B.,Han, R. W.,Xu, X. M.,Li, S. L.,Wang, J. Q.,Huang, L. C.,Cheng, J. B.,Zheng, B. Q.,Huang, L. C.,Zheng, N.,Wen, F.,Han, R. W.,Xu, X. M.,Li, S. L.,Wang, J. Q.,Wang, J. Q.. 2014

[10]Validated hydrophilic interaction LC-MS/MS method for simultaneous quantification of dacarbazine and 5-amino-4-imidazole-carboxamide in human plasma. Yang, Yuhui,Zhang, Weihua,Liu, Yanhong.

[11]Rapid and accurate determination of dichlorvos in water by liquid chromatography-electrospray ionization-tandem mass spectrometry. Yang, Lan,Liu, Yan Hong,An, Li Zhe,Li, You-bin.

[12]A sensitive chemiluminescence enzyme immunoassay based on molecularly imprinted polymers solid-phase extraction of parathion. Chen, Ge,Jin, Maojun,Du, Pengfei,Zhang, Chan,Cui, Xueyan,Zhang, Yudan,She, Yongxin,Shao, Hua,Jin, Fen,Wang, Shanshan,Zheng, Lufei,Wang, Jing.

[13]Validated hydrophilic interaction LC-MS/MS method for determination of N-methyl-2-pyrrolidinone residue. Applied to a depletion study of N-methyl-2-pyrrolidinone in swine liver following intramuscular administration of drug N-methyl-2-pyrrolidinone formulation. Liu, Yanhong,Ji, Yanhong,Chen, Jingtao,Chen, Ximing,Wang, Guangxiang,Shang, Youjun,Liu, Xiangtao,Pan, Jack. 2010

[14]Phage-Displayed Peptide That Mimics Aflatoxins and Its Application in Immunoassay. Wang, Yanru,Zhang, Qi,Wang, Yanru,Li, Peiwu,Wang, Yanru,Li, Peiwu,Zhang, Qi,Wang, Yanru,Li, Peiwu,Wang, Hong,Kim, Hee Jou,Gee, Shirley J.,Hammock, Bruce D.,Wang, Hong,Kim, Hee Jou,Gee, Shirley J.,Hammock, Bruce D..

[15]Validated hydrophilic interaction LC-MS/MS method for determination of 2-pyrrolidinone residue: Applied to a depletion study of 2-pyrrolidinone in swine liver. Liu, Yanhong,Chen, Ximing,Ji, Yanhong,Chen, Jiangtao,Wang, Guangxiang,Shang, Youjun,Liu, Xiangtao,Pan, Jack.

[16]Simultaneous determination of 13 phytohormones in oilseed rape tissues by liquid chromatography-electrospray tandem mass spectrometry and the evaluation of the matrix effect. Fan, Sufang,Wang, Xiupin,Li, Peiwu,Zhang, Qi,Zhang, Wen,Fan, Sufang,Wang, Xiupin,Li, Peiwu,Zhang, Qi,Zhang, Wen,Fan, Sufang,Wang, Xiupin,Li, Peiwu.

[17]Near-infrared-excitable acetylcholinesterase-activated fluorescent probe for sensitive and anti-interference detection of pesticides in colored food. Zhenghao Wu,Zhenxia Hao,Yunfeng Chai,Aiping Li,Chen Wang,Xiangchun Zhang,Hongping Chen,Chengyin Lu. 2023

[18]Multicolor aptasensors for pesticide multiresidues detection in agricultural products using bioorthogonal surface-enhanced Raman scattering tags. Mengmeng Yan,Hao Wang,Min Li,Wenjun Zhang,Hongxia Du,Zilei Chen,Chao Zhu,Yongxin She. 2023

[19]Evaluation of clean-up procedures and sample dilution in multi-residue pesticide analysis of spices and herbs by UPLC-MS/MS. Yuxiao Zhu,Fengshou Dong,Xingang Liu,Xiaohu Wu,Jun Xu,Yongquan Zheng. 2021

[20]Method development, validation, and risk assessment of multiple pesticide residues of fruits in China. Yan, Zhen,Nie, Jiyun,Cheng, Yang,Han, Lingxi,Farooq, Saqib. 2024

作者其他论文 更多>>