Mg-modified biochar increases adsorption and retention of nitrogen and phosphorus in greenhouse vegetable soil
文献类型: 外文期刊
作者: Yaling Wang;Yuyang Cheng;He Wang;Zhengping Peng;Xinyue Wen;Xiuwen Mei;Chunjing Liu;Xiubin Wang
作者机构:
关键词: Adsorption;Greenhouse vegetable soil;Mg-modified biochar;Nitrogen/phosphorus;Retention
期刊名称: Environmental Technology and Innovation
ISSN: 2352-1864
年卷期: 2025 年 40 卷
页码:
收录情况: SCIE(2025版) ; ; EI(2025版)
摘要: High accumulation of nitrogen (N) and phosphorus (P) in greenhouse vegetable soils raises leaching risks. Metal-modified biochar can enhance soil adsorption of either N or P, but its adsorption and retention effects under the addition of dual-solute (N and P) remain unclear. In this study, raw biochar (BC) was prepared by pyrolyzing sheep manure at 550°C under N₂ atmosphere, while Mg-modified biochar (Mg-BC) was synthesized by mixing BC with 0.5 mol L−1 MgCl₂. Adsorption isotherms, soil column leaching, and pot experiments were conducted to explore their effects on the adsorption and retention of N and P in greenhouse vegetable soil under co-existing addition of N and P solutes. Results showed that the Mg-BC treatment contained more surface oxygen-containing groups and MgO/Mg(OH)₂ crystals. According to the Langmuir model, the maximum adsorption capacities of Mg-BC for NO₃⁻ and PO₄³ ⁻ were 1.38 and 1.84 times those of BC, respectively. Soil column leaching experiments showed that the Mg-BC treatment reduced total N and P leaching losses by 30.98 % and 51.25 % compared to BC, effectively inhibiting NO₃⁻-N, dissolved inorganic N, and soluble reactive P leaching. Additionally, compared to BC, Mg-BC increased pakchoi biomass by 17.28 % and enhanced soil NO₃⁻-N, ammonium N, and available P (AP) by 128.22 %, 44.67 %, and 52.94 %, respectively. Overall, Mg-BC exhibits dual functions in N/P adsorption and nutrient availability enhancement, guiding future research on optimizing modified biochar and promoting sustainable greenhouse vegetable production.
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