数字农科院2.0

The Mesoporous Polydopamine-Based Bowl-like Lipase Nanoreactor for the Biocatalytic Synthesis of Oleate Sterol Ester

文献类型： 外文期刊

作者： Hou, Huaqing;Zhang, Shan;Zhao, Baozhu;Mao, Jin;Zhou, Qi;Deng, Qianchun;Zheng, Lei;Shi, Jie

作者机构：

关键词： polydopamine;bowl-like;mesoporous nanocarriers;lipase;phytosterol esters

期刊名称： ACS FOOD SCIENCE & TECHNOLOGY

ISSN：

年卷期： 2023 年

页码：

收录情况： 不在遴选数据库范围（2023版）

摘要： Enzymatic esterification of phytosterols is essentialfor theirstability and bioavailability in lipophilic foods. In this study,we created a new polydopamine-based bowl-like mesoporous carrier (BLM-PDA)for lipase loading and catalyzed the esterification of phytosterolsand oleic acid to produce oleate sterol ester. Candida rugosa lipase (CRL) was selected to immobilize the polymer using physicaladsorption. SEM, TEM, XRD, TGA, XPS, FT-IR, and BET were used to characterizeit in order to confirm the successful preparation. These less-studiedasymmetric bowl-like particles showed much enhanced performance inall aspects. According to the findings, BLM-PDA had a lipase loadingof around 126.05 mg g(-1), and the thermal stabilityand reusability of BLM-PDA@CRL fared particularly well in activitytests. After 55 h, the catalyst successfully completed the oleatesterol ester yield of 81.07% of the transesterification cycle at 40 & DEG;C. Therefore, it offers more suggestions for using an immobilizedlipase nanoreactor to the biosynthesis of sterol esters.

分类号：

  • 相关文献

[1]Lipase-Entrapped Polydopamine (PDA) Nanobottles for Near-Infrared (NIR)-Triggered Pickering Interfacial Biocatalysis (PIB). Xingxing Ding,Zhonglin He,Jin Mao,Qi Zhou,Qianchun Deng,Lei Zheng,Jie Shi. 2024

[2]Preparation of phytosterol esters based on food-grade Pickering emulsion stabilized by lipase-adsorbed zein-hydroxypropyl chitosan nanoparticles. Zhouliang Sun,Yufei Zhang,Huanyu Zheng,Yi Zhang,Yang Li,Mingming Zheng. 2025

[3]植物甾醇脂肪酸酯的功效和合成方法的研究进展(英文). 王明霞,黄沁洁,王江薇,黄凤洪. 2007

[4]Production of Novel "Functional Oil" Rich in Diglycerides and Phytosterol Esters with "One-Pot" Enzymatic Transesterification. Zheng, Ming-Ming,Huang, Qing,Huang, Feng-Hong,Guo, Ping-Mei,Xiang, Xia,Deng, Qitan-Chun,Li, Wen-Lin,Wan, Chu-Yun,Zheng, Chang.

[5]Lipid-AuNPs@PDA Nanohybrid for MRI/CT Imaging and Photothermal Therapy of Hepatocellular Carcinoma. Zeng, Yongyi,Zhang, Xiang,Li, Ling,Zeng, Yongyi,Zhang, Da,Wu, Ming,Li, Ling,Liu, Xiaolong,Zeng, Yongyi,Zhang, Da,Wu, Ming,Li, Ling,Liu, Xiaolong,Liu, Ying,Li, Zheng,Wei, Xueyong,Han, Xiao. 2014

[6]Ultrasonic pretreatment for lipase-catalyed synthesis of phytosterol esters with different acyl donors. Zheng, Ming-Ming,Wang, Lian,Huang, Feng-Hong,Dong, Ling,Guo, Ping-Mei,Deng, Qian-Chun,Li, Wen-Lin,Zheng, Chang.

[7]Preparation And Physicochemical Characteristics Of T.hermo-Responsive Emamectin Benzoatemicrocapsules. Shen, Y, Wang, Y, Zhao, X, Sun, CJ, Cui, B, Gao, F, Zeng, ZH, Cui, HX. 2017

[8]Highly sensitive magnetic relaxation sensing method for aflatoxin B1 detection based on Au NP-assisted triple self-assembly cascade signal amplification. Feng Hong,Chenxi Huang,Long Wu,Miao Wang,Yiping Chen,Yongxin She. 2021

[9]Deacidification of high-acid rice bran oil by the tandem continuous-flow enzymatic reactors. Liujia Xu,Yi Zhang,Vladimir Zivkovic,Mingming Zheng. 2022

[10]Mussel-inspired triple bionic adsorbent: Facile preparation of layered double hydroxide@polydopamine@metal-polyphenol networks and their selective adsorption of dyes in single and binary systems. Mingkun Gao,Donghui Xu,Yuhang Gao,Ge Chen,Rongqi Zhai,Xiaodong Huang,Xiaomin Xu,Jing Wang,Xin Yang,Guangyang Liu. 2021

[11]Hollow Hierarchical Porous and Antihydrolytic Spherical Zeolitic Imidazolate Frameworks for Enzyme Encapsulation and Biocatalysis. Zhao, Baozhu,Yang, Haowen,Mao, Jin,Zhou, Qi,Deng, Qianchun,Zheng, Lei,Shi, Jie. 2024

[12]Identification and Nontargeted Screening of Phytosterol Esters in Oilseeds and Oils Based on Fragmentation Characteristics via Ultrahigh-Performance Liquid Chromatography High-Resolution Mass Spectrometry. Zhao, Ya,Wang, Xiupin,Li, Peiwu. 2025

[13]Kinetic-Controlled Synthesis of Walnut-like Core–Shell Magnetic Mesoporous Silica Microspheres for Enhanced Enzyme Loading and Biocatalytic Performance. Zhonglin He,Yuqi Fan,Rongju Zhou,Baozhu Zhao,Xingxing Ding,Jin Mao,Jie Shi. 2025

[14]Lipase-Catalyzed Acyl-L-Carnitines Synthesis in [Bmim]PF6 Ionic Liquid. Tian, Jin-qiang,Wang, Qiang. 2009

[15]Lipase-catalyzed acylation of l-carnitine with conjugated linoleic acid in [Bmim]PF6 ionic liquid. Tian, Jinqiang,Wang, Qiang,Tian, Jinqiang,Wang, Qiang,Zhang, Zhongyuan. 2009

[16]Microfluidic biocatalysis enhances the esterification of caffeic acid and methanol under continuous-flow conditions. Wang, Sha-Sha,Li, Zhong-Jian,Sheng, Sheng,Wu, Fu-An,Wang, Jun,Sheng, Sheng,Wu, Fu-An,Wang, Jun.

[17]A novel chemoenzymatic synthesis of propyl caffeate using lipase-catalyzed transesterification in ionic liquid. Pang, Na,Gu, Shuang-Shuang,Wang, Jun,Cui, Hong-Sheng,Wang, Fang-Qin,Liu, Xi,Zhao, Xing-Yu,Wu, Fu-An,Wu, Fu-An.

[18]From microalgae oil to produce novel structured triacylglycerols enriched with unsaturated fatty acids. Wang, Jun,Wang, Xu-Dong,Zhao, Xing-Yu,Liu, Xi,Wu, Fu-An,Wang, Jun,Wu, Fu-An,Dong, Tao.

[19]Isolation and biochemical characterization of two lipases from a metagenomic library of China Holstein cow rumen. Liu, Kailang,Wang, Jiaqi,Bu, Dengpan,Zhao, Shengguo,Yu, Ping,Li, Dan,McSweeney, Chris. 2009

[20]Lipase Diversity in Glacier Soil Based on Analysis of Metagenomic DNA Fragments and Cell Culture. Zhang Yuhong,Shi, Pengjun,Meng, Kun,Bai, Yingguo,Wang, Guozeng,Yao, Bin,Zhang Yuhong,Liu, Wanli,Zhan, Zhichun.

作者其他论文 更多>>