Fe-Al bimetallic oxides functionalized-biochar via ball milling for enhanced adsorption of tetracycline in water
文献类型: 外文期刊
作者: Tang J.;Ma Y.;Zeng C.;Yang L.;Cui S.;Zhi S.;Yang F.;Ding Y.;Zhang K.;Zhang Z.
作者机构:
关键词: Bagasse biochar;Ball milling;Bimetallic oxides;Sorption;Tetracycline
期刊名称: Bioresource technology
ISSN: 1873-2976
年卷期: 2023 年 369 卷
页码:
收录情况: SCIE(2023版) ; ; EI(2023版)
摘要: The clusters formed by modified materials on its surface makes the application of functionalized biochars in adsorption face a great challenge. Here, a facile ball milling technology was innovatively proposed to tailor Fe-Al oxides-laden bagasse biochar to fabricate a novel adsorbent (BMFA-BC). Benefited from the increased exposure of Fe-Al oxides and, more importantly, enhanced functional groups by ball milling, the adsorption capacity of BMFA-BC for aqueous tetracycline reached up to 116.6 mg g-1 at 298 K. And the adsorption performance was temperature-dependent. Characterization analysis, batch sorption (thermodynamics, kinetics, isotherms, chemical factors) as well as data modeling illustrated that this superior adsorption ability could be attributed to π-π conjugation, H-bonding, complexation as well as pore filling. BMFA-BC displayed good adsorption capacity in multiple aqueous environments. The excellent regeneration ability, magnetic susceptibility ensured its viability for sustainable pollutants removal. These superiorities revealed that BMFA-BC was a suitable sorbent for antibiotics elimination. Copyright © 2022 Elsevier Ltd. All rights reserved.
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