数字农科院2.0

Synthesis and Insecticidal Activities of Novel Sulfur(oxygen) Containing Oxime Ethers as well as Structure Activity Relationship

文献类型: 外文期刊

作者: Wang Xiao-Guang;Ou Xiao-Ming;Liu Shu-Dong;Mo Hong-Bo;Liu Xin-Ping;Wang Ting-Jin;He Hai-Jun;Hu Li;Huang Ming-Zhi;Liu Ai-Ping;Wang Ting-Jin;Liu Zhao-Jie;Yao Jian-Ren;Mo Hong-Bo;He Hai-Jun;Yao Jian-Ren

作者机构:

关键词: sulfur(oxygen) containing oxime ether;insecticidal activity;homoptera;lepidoptera

期刊名称: CHINESE JOURNAL OF ORGANIC CHEMISTRY

ISSN: 0253-2786

年卷期: 2008 年 28 卷 10 期

页码:

收录情况: SCI

摘要: 96 novel sulfur(oxygen) containing 1-aryl O-benzyl oximes were synthesized by the reaction of sulfur(oxygen) containing 1-aryl oximes with the corresponding halides of pyrethriod alcohols in the presence of sodium hydroxide and phase transfer catalyst or with triethylquaternary ammonium salts of halides of pyrethriod alcohol in the presence of sodium hydroxide. The title compounds were identified by MS, (1)H NMR, IR spectra and elemental analyses. Bioassay showed that these compounds showed remarkable insecticidal activities against homopteran and lepidopteran pests. C(74) and C(93) showed a medial effective dose [LC(50)/(mg.L(-1))] of 1.4, 0.63 and 0.31, 1.2 against oriental army worm and leafhopper respectively, the LC(50) values of compounds C(74) and C(93) were better than that of the commercialized insecticide fenvalerate.

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