A temperature-responsive mixed matrix membrane based on poly(ionic liquid)@poly(N-isopropylacrylaminde) microgels and polyvinylidene fluoride for the selective separation of citrus flavonoids
文献类型: 外文期刊
作者: Zongkui Qin;Tian Lei;Shanshan Wang;Leilei Liu;Zhijian Tan
作者机构:
关键词: Bioactive compounds;Citrus flavonoids;Membrane separation;Poly(ionic liquid)s;Temperature-responsive mixed matrix membranes
期刊名称: Microchemical Journal
ISSN: 0026-265X
年卷期: 2024 年 199 卷
页码:
收录情况: SCIE(2024版)
摘要: Herein, four novel poly(ionic liquid)@poly(N-isopropylacrylaminde) microgels were prepared and doped into polyvinylidene fluoride (PVDF) to fabricate eight temperature-responsive mixed matrix membranes (TRMs) for the efficient separation of natural citrus flavonoids, viz. naringin, neohesperidin, naringenin, and hesperetin. Dynamic light scattering of microgels in water at 20 and 50 ℃ confirmed their temperature-responsive properties. Water flux of TRMs at different temperatures proved their switchable response characteristic between 30 and 35 ℃. The mechanical property, pore size distribution, porosity, and specific surface area of these TRMs were measured. Moreover, the chemical structure, microstructure, hydrophobicity, thermostability, anti-fouling performance, and charge property were also confirmed for them. The M4 membrane exhibited a maximum separation selectivity of 81.66% at 20 ℃. Binding energy of G4 microgel to flavanone glycosides through H-bonding was greater than that of G4/flavanones. These TRMs, as a kind of novel separation materials, have the potential in the separation of various natural products.
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