Fe oxides simultaneously improve stability of Cd and carbon in paddy soil:The underlying influence at aggregate level
文献类型: 外文期刊
作者: Shanshan Li;Yang Fei;Chen Wang;Jiajun Sun;Jiahui Liang;Yao Feng;Bing Yang;Meng Wang;Huading Shi;Shibao Chen
作者机构:
关键词: Aggregate;Cadmium;Iron oxides;Paddy soil;Soil organic carbon
期刊名称: Journal of Hazardous Materials
ISSN: 0304-3894
年卷期: 2024 年 477 卷
页码:
收录情况: SCIE(2024版) ; ; EI(2024版)
摘要: Iron (Fe) oxides have a strong adsorption affinity for Cd and organic carbon (SOC). However, under alternate wet-dry (IF) condition,the influences of Fe oxides on the speciation and disrtribution of Cd and SOC in soil aggregates are unkown. In the present study, soils untreated (S), removed (S-Fe) or added (S+Fe) Fe oxide soils were blended with cadmium chloride solution and cultivated for 56 days under different moisture management practices. Compared with the S-Fe soil, the IF treatment increased the contents of Fe oxide-bound SOC (Fe-OC) and Fe/Mn oxide-bound Cd (Fe/Mn-Cd) by 18.5–29.8-fold and 1.45–2.45-fold, repectively, in the S and S+Fe soils, corresponding to a 36 %−42 % increase in the recalcitrant C pool (RCP) and a 53 %−87 % decrease in the exchangeable Cd content. These results could be attributed to soil particle aggregation and Fe redistribution. Fe addition promoted the transfer of Cd/SOC accumulated in microaggregates to macroaggregates and increased the variable negative charge content in macroaggregates and the adsorption capacity of macroaggregates for Cd/SOC. More Cd/SOC accumulated in macroaggregates in Fe oxide-bound form, which reduced the risk of Cd migration and Cd availability and increased the physical protection of SOC. Therefore, Fe oxide has great potential to simultaneously reduce carbon emissions and cadmium toxicity in paddy soil.
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